(η5-Cyclopentadienyl)(η6-mesitylamine)ruthenium(II) hexafluoridophosphate
نویسندگان
چکیده
The title compound, [Ru(η(5)-C(5)H(5)){η(6)-C(6)H(2)(CH(3))(3)NH(2)}]PF(6), contains a sandwich complex with a mesitylamine unit which is significantly non-planar at the ipso-carbon of the amino group due to repulsive electronic effects with Ru. The ipso-carbon deviates by 0.107 (3) Å from the least-squares plane of the remaining five benzene ring atoms, which show an r.m.s. deviation of 0.005 Å. N-H⋯F hydrogen-bonding interactions help to consolidate the crystal packing.
منابع مشابه
(η5-Cyclopentadienyl)[η6-diethyl ethyl(phenyl)malonate]iron(II) hexafluoridophosphate
At 223 (2) K, the complexed rings in the iron(II) complex cation of the title salt, [Fe(C(5)H(5))(C(15)H(20)O(4))]PF(6), are almost parallel [dihedral angle between planes = 4.10 (14)°]. Among the C atoms of the complexed arene ring, the quaternary C atom is located at the longest distance from the Fe atom. The F atoms of the PF(6) (-) anion were found to be equally disordered over two sites.
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